Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, People's Republic of China.
Org Biomol Chem. 2012 Dec 21;10(47):9410-7. doi: 10.1039/c2ob26463c. Epub 2012 Oct 30.
An easily available Pd(OAc)(2)/(2-mesitylindenyl)dicyclohexylphosphine/Me(octyl)(3)N(+)Cl(-)/K(3)PO(4)·3H(2)O catalytic system was developed and it shows high catalytic activity in the Suzuki-Miyaura cross-coupling reaction of a diverse array of aryl and heteroaryl chlorides in water. Notably, this catalytic system also works with ultra-low loading of the catalyst with high turnover numbers.
开发了一种易得的 Pd(OAc)(2)/(2-甲基茚基)二环己基膦/Me(octyl)(3)N(+)Cl(-)/K(3)PO(4)·3H(2)O 催化体系，该体系在水中对各种芳基和杂芳基氯的 Suzuki-Miyaura 交叉偶联反应具有很高的催化活性。值得注意的是，该催化体系在超低催化剂负载量下也具有高周转数。
