钴(II)催化的有机硼酸对活化烯烃的 1,4-加成反应：在高顺式立体选择性合成氨基茚烷羧酸衍生物中的应用。
Cobalt(II)-catalyzed 1,4-addition of organoboronic acids to activated alkenes: an application to highly cis-stereoselective synthesis of aminoindane carboxylic acid derivatives.
机构信息
Department of Chemistry, National Tsing Hua University, Hsinchu, 30013, Taiwan.
出版信息
Chemistry. 2012 Nov 19;18(47):14918-22. doi: 10.1002/chem.201202575. Epub 2012 Oct 30.
PMID:23112007
Abstract
It all adds up: The 1,4-addition of organoboronic acids to activated alkenes catalyzed by [Co(dppe)Cl(2)] is described. A [3+2]-annulation reaction of ortho-iminoarylboronic acids with acrylates to give various aminoindane carboxylic acid derivatives with cis-stereoselectivity is also demonstrated (see scheme; dppe = 1,2-bis(diphenylphosphino)ethane).
摘要
所有这些加起来
描述了[Co(dppe)Cl(2)]催化的有机硼酸与活化烯烃的 1,4-加成。邻亚胺基芳基硼酸与丙烯酸酯的[3+2]-环化反应也证明了具有顺式立体选择性的各种氨基茚烷羧酸衍生物的生成（见方案；dppe = 1,2-双（二苯基膦基）乙烷）。
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