钴配合物催化的有机硼酸和醛合成联芳基酮和邻苯二甲酸酯。
Synthesis of biarylketones and phthalides from organoboronic acids and aldehydes catalyzed by cobalt complexes.
机构信息
Department of Chemistry, National Tsing Hua University, Hsinchu, 30013, Taiwan.
出版信息
Chem Commun (Camb). 2011 Oct 7;47(37):10461-3. doi: 10.1039/c1cc13771a. Epub 2011 Aug 18.
PMID:21850348
Abstract
A cobalt-catalyzed addition of aryl- and alkenylboronic acids to aldehydes and phthalaldehyde to give the corresponding biarylketones and 3-aryl phthalides in good to excellent yields in one pot is described.
摘要
描述了一种钴催化的芳基和烯基硼酸与醛以及邻苯二醛的加成反应，一锅法以良好到优异的收率得到相应的联苯甲酮和 3-芳基邻苯二甲酸酐。
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