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2-[(苯胺基)(2-硝基苯基)甲基]环己酮

2-[(Anilino)(2-nitro-phen-yl)meth-yl]cyclo-hexa-none.

作者信息

Eftekhari-Sis Bagher, Mohajer Sahar, Büyükgüngör Orhan

机构信息

Department of Chemistry, University of Maragheh, Maragheh, Iran.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Oct 1;68(Pt 10):o2829. doi: 10.1107/S1600536812036859. Epub 2012 Sep 1.

DOI:10.1107/S1600536812036859
PMID:23125635
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3470191/
Abstract

In the title compound, C(19)H(20)N(2)O(3), the cyclo-hexa-none ring adopts a chair conformation with the amino-methyl group is positioned equatorially. An intra-molecular N-H⋯O hydrogen bond occurs. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds.

摘要

在标题化合物C(19)H(20)N(2)O(3)中，环己酮环呈椅式构象，氨甲基位于平伏键位置。存在分子内N-H⋯O氢键。在晶体中，分子通过N-H⋯O氢键相连。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13e4/3470191/9ceb97639bfc/e-68-o2829-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13e4/3470191/82d119962291/e-68-o2829-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13e4/3470191/9ceb97639bfc/e-68-o2829-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13e4/3470191/82d119962291/e-68-o2829-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13e4/3470191/9ceb97639bfc/e-68-o2829-fig2.jpg

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本文引用的文献

1
Modern Variants of the Mannich Reaction.曼尼希反应的现代变体
Angew Chem Int Ed Engl. 1998 May 4;37(8):1044-1070. doi: 10.1002/(SICI)1521-3773(19980504)37:8<1044::AID-ANIE1044>3.0.CO;2-E.
2
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Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 18;65(Pt 3):o539-40. doi: 10.1107/S1600536809004954.
3
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
4
Synthesis and anti-inflammatory evaluation of methylene bridged benzofuranyl imidazo[2,1-b][1,3,4]thiadiazoles.亚甲基桥连苯并呋喃基咪唑并[2,1-b][1,3,4]噻二唑的合成与抗炎活性评价
Eur J Med Chem. 2008 Aug;43(8):1721-9. doi: 10.1016/j.ejmech.2007.06.023. Epub 2007 Jul 12.
5
Highly efficient one-pot three-component Mannich reaction in water catalyzed by heteropoly acids.杂多酸催化水中高效一锅三组分曼尼希反应。
Org Lett. 2006 May 11;8(10):2079-82. doi: 10.1021/ol060498v.
6
The direct catalytic asymmetric mannich reaction.直接催化不对称曼尼希反应。
Acc Chem Res. 2004 Feb;37(2):102-12. doi: 10.1021/ar030231l.