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1-（3-苄基-4,6-二苄氧基-2-羟基苯基）乙酮

1-(3-Benzyl-4,6-dibenz-yloxy-2-hy-droxy-phen-yl)ethanone.

作者信息

Hill Tania N, Kuo C-M, Bezuidenhoudt Barend C B

机构信息

Department of Chemistry, University of the Free State, PO Box 339, Bloemfontein 9300, South Africa.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Oct 1;68(Pt 10):o2863. doi: 10.1107/S160053681203588X. Epub 2012 Sep 5.

DOI:10.1107/S160053681203588X
PMID:23125664
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3470220/
Abstract

The title compound, C(29)H(26)O(4), is essentially planar in the acetophenone portion that includes both the hy-droxy and a benz-yloxy O atoms, with an r.m.s. deviation of 0.0311 Å. The other two substituents inter-sect the plane at 70.45 (3) and 59.55 (4)°. In the molecule there is an intramolecular O-H⋯O hydrogen bond. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds, as well as C-H⋯π and π-stacking inter-actions, with centroid-centroid distances 3.6570 (2) Å.

摘要

标题化合物C(29)H(26)O(4)在包含羟基和苄氧基O原子的苯乙酮部分基本呈平面结构，均方根偏差为0.0311 Å。另外两个取代基与该平面的夹角分别为70.45 (3)°和59.55 (4)°。分子内存在O-H⋯O氢键。在晶体中，分子通过C-H⋯O氢键以及C-H⋯π和π-堆积相互作用相连，质心间距为3.6570 (2) Å。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f1cf/3470220/c6028d2a8981/e-68-o2863-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f1cf/3470220/60add7e7242a/e-68-o2863-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f1cf/3470220/1e39045ba291/e-68-o2863-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f1cf/3470220/4a0b12272aca/e-68-o2863-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f1cf/3470220/c6028d2a8981/e-68-o2863-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f1cf/3470220/60add7e7242a/e-68-o2863-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f1cf/3470220/1e39045ba291/e-68-o2863-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f1cf/3470220/4a0b12272aca/e-68-o2863-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f1cf/3470220/c6028d2a8981/e-68-o2863-fig4.jpg

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