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[火灾期间氢氰酸形成的意义]

[Significance of hydrocyanic acid formation during fires].

作者信息

von Meyer L, Drasch G, Kauert G

出版信息

Z Rechtsmed. 1979;84(1):69-73. doi: 10.1007/BF02091986.

DOI:10.1007/BF02091986
PMID:231350
Abstract

Cyanide concentrations of blood samples from fire victims autopsied in the Institute of Legal Medicine, Munich, have been determined. In 25% of 48 analyzed cases cyanide concentrations from 0.52 microgram to 6.24 microgram Cyanide/ml blood have been detected. These results are compared to former studies and the higher mean level in our collective is emphasized. The importance of hydrocyanid acid in the toxicity of fire gases is evidently greater, than assumed. Hydrocyanic acid may be produced from nitrogen continaing polymers during combustion. The quote of these polymers in clothing, furniture, and also in equipment of cars is increasing. Therefore, it is necessary to take more notice of the formation of hydrocyanic acid during combustion, even though carbon monoxide is in general the main toxic agent in fire gases.

摘要

已对在慕尼黑法医学研究所进行尸检的火灾受害者血液样本中的氰化物浓度进行了测定。在48例分析病例中,25%的病例检测到血液中氰化物浓度为0.52微克至6.24微克氰化物/毫升。将这些结果与以前的研究进行了比较,并强调了我们样本中较高的平均水平。氢氰酸在火灾气体毒性中的重要性显然比假设的要大。燃烧过程中含氮聚合物可能产生氢氰酸。这些聚合物在服装、家具以及汽车设备中的占比正在增加。因此,即使一氧化碳通常是火灾气体中的主要有毒物质,也有必要更多地关注燃烧过程中氢氰酸的形成。

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1
[Significance of hydrocyanic acid formation during fires].[火灾期间氢氰酸形成的意义]
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2
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引用本文的文献

1
[Cyanide poisoning: forensic toxicology observations in the study of 54 cases of fatal poisoning].
Z Rechtsmed. 1985;95(1):35-43. doi: 10.1007/BF00203850.

本文引用的文献

1
The occurrence of cyanide in the blood of fire victims.火灾受害者血液中氰化物的出现情况。
J Forensic Sci. 1966 Apr;11(2):167-73.
2
[Combined carbon monoxide/cyanide intoxication due to combustion of plastic material (author's transl)].塑料材料燃烧导致的一氧化碳/氰化物混合中毒(作者译)
Z Rechtsmed. 1977 Jan 21;79(1):69-71.
3
Spectrophotometric determination of cyanide in biological materials.分光光度法测定生物材料中的氰化物。
J Forensic Sci. 1977 Apr;22(2):443-5.
4
Exposure of firefighters to toxic air contaminants.消防员接触有毒空气污染物的情况。
Am Ind Hyg Assoc J. 1978 Jul;39(7):534-9. doi: 10.1080/0002889778507805.
5
Occupational exposures to cyanide in Baltimore fire fighters.巴尔的摩消防员的职业性氰化物暴露。
J Occup Med. 1978 Jan;20(1):53-6. doi: 10.1097/00043764-197801000-00011.
6
[Experimental studies on the toxicity of smoldering and burning gases of different materials].[不同材料阴燃和燃烧气体毒性的实验研究]
Arch Kriminol. 1975 Jul-Aug;156(1-2):15-23.
7
Cyanide exposure in fires.
Lancet. 1978 Jul 8;2(8080):91-2. doi: 10.1016/s0140-6736(78)91398-3.