铜促进的伯、仲烷基硼酸的三氟甲基化反应。
Copper-promoted trifluoromethylation of primary and secondary alkylboronic acids.
机构信息
Department of Chemistry, University of Science and Technology of China, Hefei 230026, China.
出版信息
Angew Chem Int Ed Engl. 2012 Dec 7;51(50):12551-4. doi: 10.1002/anie.201206681. Epub 2012 Nov 9.
PMID:23143929
Abstract
New couple: The Cu-promoted trifluoromethylation of primary and secondary alkylboronic acids with TMSCF(3) extends the scope of transition-metal-catalyzed trifluoromethylation reactions to sp(3)-hybridized carbon centers. It also represents one of the first examples for Cu-catalyzed C-C cross-coupling reactions of alkylboronic acid derivatives.
摘要
新夫妇
Cu 促进的伯、仲烷基硼酸与 TMSCF(3)的三氟甲基化反应将过渡金属催化的三氟甲基化反应的范围扩展到 sp(3)杂化的碳中心。它也是首例 Cu 催化的烷基硼酸衍生物 C-C 交叉偶联反应之一。
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