Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, People's Republic of China.
Org Lett. 2011 May 6;13(9):2342-5. doi: 10.1021/ol2005903. Epub 2011 Apr 7.
A copper-catalyzed trifluoromethylation of aryl- and alkenylboronic acids with Togni's reagent was described. The reaction proceeded in good to excellent yields for a range of different substrates including heteroarylboronic acids and substrates with a variety of functional groups under mild reaction conditions.
本文描述了 Togni 试剂促进的芳基和烯基硼酸的铜催化三氟甲基化反应。在温和的反应条件下，该反应对于一系列不同的底物（包括杂芳基硼酸和具有各种官能团的底物）具有良好到优秀的产率。
