Department of Chemistry, Northeast Normal University, 5268 Renmin Street, Changchun, 130024, China.
Chem Soc Rev. 2013 Feb 7;42(3):1251-86. doi: 10.1039/c2cs35329f.
Ketene dithioacetals are versatile intermediates in organic synthesis. Extensive research, since the last decade, has given rise to new prospects in their chemistry. The objective of this review is twofold: first, to highlight the new prospects in the chemistry of functionalized ketene dithioacetals, and second, to provide an intrinsic link between ketene dithioacetal groups and a variety of other functional groups, which has brought out many new facts that will assist in future designs.
烯酮二硫缩醛是有机合成中用途广泛的中间体。在过去的十年中,对它们的化学性质进行了广泛的研究,为其化学性质带来了新的前景。本次综述的目的有两个:首先,强调功能化烯酮二硫缩醛化学的新前景;其次,在烯酮二硫缩醛基团和各种其他官能团之间建立内在联系,这揭示了许多新的事实,将有助于未来的设计。