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硅溶胶和硅钛溶胶-凝胶材料:合成与分析应用。

Silica and silica-titania sol-gel materials: synthesis and analytical application.

机构信息

Analytical Chemistry Division, Department of Chemistry, Lomonosov Moscow State University, Leninskie gory, 1/3, Moscow 119991, Russia.

出版信息

Talanta. 2012 Dec 15;102:114-22. doi: 10.1016/j.talanta.2012.07.043. Epub 2012 Aug 1.

Abstract

This review describes last decade progress in the synthesis of sol-gel materials with analytically relevant properties and their application for the determination of metal ions, non-metal and organic compounds. The following types of materials are discussed: silica sol-gel materials doped with various analytical reagents, organofunctional silica sol-gel materials, and silica titania sol-gel materials. The variety of obtained materials allows their application for a wide range of analytical systems: electrochemical sensors, solid phase spectrophotometrical and SIA determination, and also for test determination including the employment of "length-of-stain" indicator tubes. This review surveys the results of studies on mentioned above subjects and summarizes the works accomplished in the field by author's team in Moscow State University.

摘要

本综述描述了过去十年中具有分析相关性质的溶胶-凝胶材料的合成及其在测定金属离子、非金属和有机化合物方面的应用进展。讨论了以下类型的材料:掺杂各种分析试剂的二氧化硅溶胶-凝胶材料、有机官能团二氧化硅溶胶-凝胶材料和二氧化钛硅溶胶-凝胶材料。所获得的材料种类繁多,可应用于广泛的分析系统:电化学传感器、固相分光光度和 SIA 测定,以及包括使用“染色长度”指示剂管的测试测定。本综述综述了上述主题的研究结果,并总结了莫斯科国立大学作者团队在该领域完成的工作。

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