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脉冲电场(PEF)处理下卵磷脂的电化学反应和氧化。

Electrochemical reaction and oxidation of lecithin under pulsed electric fields (PEF) processing.

机构信息

State Key Laboratory of Food Science and Technology and School of Food Science and Technology, Jiangnan University, No. 1800 Lihu Road, Wuxi 214122, China.

出版信息

J Agric Food Chem. 2012 Dec 12;60(49):12204-9. doi: 10.1021/jf304236h. Epub 2012 Dec 4.

Abstract

Pulsed electric fields (PEF) processing is a promising nonthermal food preservation technology, which is ongoing from laboratory and pilot plant scale levels to the industrial level. Currently, greater attention has been paid to side effects occurring during PEF treatment and the influences on food qualities and food components. The present study investigated the electrochemical reaction and oxidation of lecithin under PEF processing. Results showed that electrochemical reaction of NaCl solutions at different pH values occurred during PEF processing. Active chlorine, reactive oxygen, and free radicals were detected, which were related to the PEF parameters and pH values of the solution. Lecithin extracted from yolk was further selected to investigate the oxidation of food lipids under PEF processing, confirming the occurrence of oxidation of lecithin under PEF treatment. The oxidative agents induced by PEF might be responsible for the oxidation of extracted yolk lecithin. Moreover, this study found that vitamin C as a natural antioxidant could effectively quench free radicals and inhibit the oxidation of lipid in NaCl and lecithin solutions as model systems under PEF processing, representing a way to minimize the impact of PEF treatment on food qualities.

摘要

脉冲电场(PEF)处理是一种有前途的非热食品保鲜技术,正在从实验室和中试工厂规模向工业规模发展。目前,人们越来越关注 PEF 处理过程中发生的副作用以及对食品质量和成分的影响。本研究探讨了 PEF 处理下卵磷脂的电化学反应和氧化作用。结果表明,在 PEF 处理过程中,不同 pH 值的 NaCl 溶液会发生电化学反应。检测到活性氯、活性氧和自由基,它们与 PEF 参数和溶液的 pH 值有关。从蛋黄中提取的卵磷脂进一步被选择来研究 PEF 处理下食品脂质的氧化,证实了在 PEF 处理下卵磷脂的氧化发生。PEF 诱导的氧化剂可能是导致蛋黄卵磷脂提取氧化的原因。此外,本研究发现,维生素 C 作为一种天然抗氧化剂,可有效淬灭自由基,并抑制 NaCl 和卵磷脂溶液中脂质的氧化,作为 PEF 处理下的模型体系,代表了一种最小化 PEF 处理对食品质量影响的方法。

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