不对称膦-Diels-Alder 反应：通过立体化学非对映面差异实现 P-手性膦烷的立体选择性方法。
Asymmetric phospha-Diels-Alder reaction: a stereoselective approach towards P-chiral phosphanes through diastereotopic face differentiation.
机构信息
Universität Leipzig, Faculty of Chemistry and Mineralogy, Institute of Inorganic Chemistry, Germany.
出版信息
Chemistry. 2012 Dec 21;18(52):16604-7. doi: 10.1002/chem.201203671. Epub 2012 Nov 30.
PMID:23203531
Abstract
Old principles, new chemistry: a facile stereoselective synthesis of P-chiral phosphanes is described in which the principle of enantiotopic and diastereotopic face differentiation used in carbon chemistry is extended to a phosphorus atom in a planar environment, that is, 2H-phospholes.
摘要
旧原理，新化学：本文描述了一种简便的对映选择性合成 P-手性膦的方法，其中在碳化学中使用的对映面和非对映面区分原理扩展到了平面环境中的磷原子，即 2H-磷杂环戊二烯。
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