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一种电致变色离子液体：在固态平台中的设计、表征和性能。

An electrochromic ionic liquid: design, characterization, and performance in a solid-state platform.

机构信息

CLARITY: The Centre for Sensor Web Technologies, National Centre for Sensor Research, School of Chemical Sciences, Dublin City University, Dublin 9, Ireland.

出版信息

ACS Appl Mater Interfaces. 2013 Jan;5(1):55-62. doi: 10.1021/am3018948. Epub 2012 Dec 14.

DOI:10.1021/am3018948
PMID:23206366
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3542915/
Abstract

This work describes the synthesis and characteristics of a novel electrochromic ionic liquid (IL) based on a phosphonium core tethered to a viologen moiety. When integrated into a solid-state electrochromic platform, the viologen modified IL behaved as both the electrolyte and the electrochromic material. Platform fabrication was achieved through in situ photo-polymerization and encapsulation of this novel IL within a hybrid sol-gel. Important parameters of the platform performance, including its coloration efficiency, switching kinetics, and optical properties were characterised using UV-vis spectroscopy and cyclic voltammetry in tandem. The electrochromic platform exhibits a coloration efficiency of 10.72 cm(2) C(-1) and a varied optical output as a function of the incident current. Despite the rather viscous nature of the material, the platform exhibited approximately 2 orders of magnitude faster switching kinetics (221 s to reach 95 % absorbance) when compared to previously reported electrochromic ILs (18,000 s).

摘要

这项工作描述了一种新型基于磷鎓核心连接到紫罗碱部分的电致变色离子液体（IL）的合成和特性。当整合到固态电致变色平台中时，修饰后的紫罗碱 IL 既可用作电解质，也可用作电致变色材料。该新型 IL 原位光聚合和混合溶胶-凝胶封装，实现了平台的制造。通过紫外可见光谱法和循环伏安法联用，对平台性能的重要参数，包括其着色效率、开关动力学和光学性能进行了表征。电致变色平台的着色效率为 10.72 cm(2) C(-1)，其光学输出随入射电流而变化。尽管该材料的粘性相当大，但与以前报道的电致变色 IL 相比，该平台的开关动力学速度快了约 2 个数量级（达到 95%吸收率的时间为 221 s）。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11d9/3542915/704cb9e56c4a/am-2012-018948_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11d9/3542915/f2989b5c11f5/am-2012-018948_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11d9/3542915/a30fb85af49f/am-2012-018948_0009.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11d9/3542915/edb80b0e8ab9/am-2012-018948_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11d9/3542915/811b59ee19ac/am-2012-018948_0010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11d9/3542915/bb0459dfde4b/am-2012-018948_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11d9/3542915/a4ce4ea3fc24/am-2012-018948_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11d9/3542915/f921a771186c/am-2012-018948_0011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11d9/3542915/bc5d923b0661/am-2012-018948_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11d9/3542915/704cb9e56c4a/am-2012-018948_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11d9/3542915/f2989b5c11f5/am-2012-018948_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11d9/3542915/a30fb85af49f/am-2012-018948_0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11d9/3542915/47bacd101725/am-2012-018948_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11d9/3542915/edb80b0e8ab9/am-2012-018948_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11d9/3542915/811b59ee19ac/am-2012-018948_0010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11d9/3542915/bb0459dfde4b/am-2012-018948_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11d9/3542915/a4ce4ea3fc24/am-2012-018948_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11d9/3542915/f921a771186c/am-2012-018948_0011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11d9/3542915/bc5d923b0661/am-2012-018948_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/11d9/3542915/704cb9e56c4a/am-2012-018948_0007.jpg

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Chem Commun (Camb). 2011 Aug 28;47(32):9072-4. doi: 10.1039/c1cc12265g. Epub 2011 Jul 13.
2
Solvent-dependent photoresponsive conductivity of azobenzene-appended ionic liquids.含偶氮苯侧基的离子液体的溶剂依赖性光致响应电导性。
Chem Commun (Camb). 2011 Jun 21;47(23):6641-3. doi: 10.1039/c1cc11924a. Epub 2011 May 12.
3
Ionogels, ionic liquid based hybrid materials.
用于电化学储能与转换装置的离子液体基凝胶：近期进展与未来展望综述
Gels. 2021 Dec 21;8(1):2. doi: 10.3390/gels8010002.
4
Enzyme-responsive Fluorescent Ionic Liquid.酶响应型荧光离子液体
Anal Sci. 2020 Feb 10;36(2):143-145. doi: 10.2116/analsci.19C013. Epub 2020 Jan 24.
5
Viologen-Based Electrochromic Materials: From Small Molecules, Polymers and Composites to Their Applications.基于紫罗精的电致变色材料：从小分子、聚合物和复合材料到其应用
Polymers (Basel). 2019 Nov 8;11(11):1839. doi: 10.3390/polym11111839.
6
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7
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8
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Membranes (Basel). 2012 Feb 7;2(1):16-39. doi: 10.3390/membranes2010016.
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4
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5
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6
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