Atherton T J, Adler J H
Department of Physics and Astronomy, Tufts University, 4 Colby Street, Medford, Massachusetts 02155, USA.
Phys Rev E Stat Nonlin Soft Matter Phys. 2012 Oct;86(4 Pt 1):040701. doi: 10.1103/PhysRevE.86.040701. Epub 2012 Oct 18.
We show that patterned surfaces can promote bistable configurations of nematics for reasons other than the symmetry of the surface. Numerical and analytical calculations reveal that a nematic liquid crystal in contact with a striped surface is subject to the competing aligning influences of elastic anisotropy, differing energy cost of various types of deformation, and flexoelectricity, curvature-induced spontaneous polarization. These effects favor opposing ground states where the azimuthal alignment is, respectively, parallel or perpendicular to the stripes. Material parameters for which the effect might be observed lie within the range measured for bent-core nematogens.
我们表明,有图案的表面能够促进向列相的双稳态构型,其原因并非表面的对称性。数值计算和解析计算表明,与条纹表面接触的向列型液晶会受到弹性各向异性、不同类型形变的不同能量消耗以及挠曲电(曲率诱导的自发极化)的竞争排列影响。这些效应有利于方位排列分别平行或垂直于条纹的相反基态。可能观察到这种效应的材料参数处于弯核向列相液晶所测范围之内。