Institut de Ciència Molecular/Departament de Química Inorgànica, Universitat de València, c/Catedrático José Beltrán Martínez 2, 46980 Paterna, València, Spain.
Inorg Chem. 2012 Dec 17;51(24):13078-80. doi: 10.1021/ic302287w. Epub 2012 Dec 4.
Here we present a novel three-dimensional iron(II) spin-crossover porous coordination polymer based on the bis(1,2,4-triazol-4-yl)adamantane (tr(2)ad) ligand and the Au(CN)(2) metalloligand anions with the formula {Fe(3)(tr(2)ad)(4)Au(CN)(2))}Au(CN)(2)·G. The sorption/desorption of guest molecules, water, and five/six-membered-ring organic molecules is easily detectable because the guest-free and -loaded frameworks present drastically distinct coloration and spin-state configurations.
在这里，我们提出了一种新颖的基于双（1,2,4-三氮唑-4-基）金刚烷（tr(2)ad）配体和[Au(CN)(2)]（-)金属配位阴离子的新型三维铁（II）自旋交叉多孔配位聚合物，其化学式为{Fe(3)(tr(2)ad)(4)Au(CN)(2))}Au(CN)(2)·G。由于空骨架和负载骨架表现出截然不同的颜色和自旋态配置，因此很容易检测到客体分子、水和五/六元环有机分子的吸附/解吸。
