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“象草”脱木质素用于生产纤维素衍生物的研究。

Study of "napier grass" delignification for production of cellulosic derivatives.

机构信息

Departamento de Engenharia Química, Centro Universitário da FEI, Av. Humberto de Alencar Castelo Branco, 3972, 09850-901 São Bernardo do Campo, SP, Brazil.

出版信息

Carbohydr Polym. 2013 Jan 30;92(1):849-55. doi: 10.1016/j.carbpol.2012.09.095. Epub 2012 Oct 8.

Abstract

Recently, much research on the evaluation of new cellulose sources has been developed. In this context, a promising source is "napier grass", which contains 30.40% lignin, 36.34% cellulose, and 34.12% hemicellulose. In this work, conditions for the delignification of "napier grass" in the laboratory were studied by using calcium oxide (CaO) and hydrogen peroxide (H(2)O(2)). The best pulping conditions were 9.00% CaO for a period of 2.73 h, which resulted in 74.99% delignification and 66.58% cellulose. The best conditions for the bleaching process were pH 12 and hydrogen peroxide at concentration of 4.2% for 6h, at a temperature of 40 °C, which gave 90.98% delignification and 99.21% cellulose. The analyses were performed by using weight percent.

摘要

最近,人们对新的纤维素来源的评价进行了大量研究。在这方面,一种很有前途的来源是“象草”,它含有 30.40%的木质素、36.34%的纤维素和 34.12%的半纤维素。在这项工作中,通过使用氧化钙(CaO)和过氧化氢(H2O2),在实验室条件下对“象草”进行了脱木质素研究。最佳制浆条件为 9.00% CaO,时间为 2.73 小时,脱木质素率为 74.99%,纤维素为 66.58%。最佳漂白条件为 pH 值 12 和 4.2%浓度的过氧化氢,时间为 6 小时,温度为 40°C,脱木质素率为 90.98%,纤维素为 99.21%。分析采用重量百分比进行。

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