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硅表面的金属稀土硅化物纳米线。

Metallic rare-earth silicide nanowires on silicon surfaces.

机构信息

Institut für Festkörperphysik, Technische Universität Berlin, Germany.

出版信息

J Phys Condens Matter. 2013 Jan 9;25(1):014012. doi: 10.1088/0953-8984/25/1/014012. Epub 2012 Dec 5.

Abstract

The formation, atomic structure, and electronic properties of self-assembled rare-earth silicide nanowires on silicon surfaces were studied by scanning tunneling microscopy and angle-resolved photoelectron spectroscopy. Metallic dysprosium and erbium silicide nanowires were observed on both the Si(001) and Si(557) surfaces. It was found that they consist of hexagonal rare-earth disilicides for both surface orientations. On Si(001), the nanowires are characterized by a one-dimensional band structure, while the electronic dispersion is two-dimensional for the nanowires formed on Si(557). This behavior is explained by the different orientations of the hexagonal c axis of the silicide leading to different conditions for the carrier confinement. By considering this carrier confinement it is demonstrated how the one-dimensional band structure of the nanowires on Si(001) can be derived from the two-dimensional one of the silicide monolayer on Si(111).

摘要

通过扫描隧道显微镜和角分辨光电子能谱研究了硅表面自组装的稀土硅化物纳米线的形成、原子结构和电子性质。在 Si(001) 和 Si(557) 表面都观察到了金属镝和铒硅化物纳米线。结果发现,对于这两种表面取向,它们都由六方稀土二硅化物组成。在 Si(001)上,纳米线具有一维能带结构,而在 Si(557)上形成的纳米线的电子色散则是二维的。这种行为可以通过硅化物的六方 c 轴的不同取向来解释,这导致了载流子限制的不同条件。通过考虑这种载流子限制,可以证明 Si(001)上纳米线的一维能带结构如何从 Si(111)上硅化物单层的二维能带结构中推导出来。

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引用本文的文献

1
Spectroscopic Analysis of Rare-Earth Silicide Structures on the Si(111) Surface.
Materials (Basel). 2021 Jul 23;14(15):4104. doi: 10.3390/ma14154104.

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