State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, PR China.
Chem Commun (Camb). 2013 Jan 25;49(7):698-700. doi: 10.1039/c2cc37587g.
The tandem Pauson-Khand type reactions of 1,4-enynes tethered by a cyclopropyl group with two molecules of CO proceed smoothly in the presence of Rh(CO)(2)Cl under a CO atmosphere to give the corresponding 6-hydroxy-2,3-dihydro-1H-inden-1-one derivatives in moderate yields under mild conditions.
在 CO 气氛下，Rh(CO)(2)Cl的存在下，通过环丙基连接的 1,4-烯炔的串联 Pauson-Khand 型反应能够顺利进行，以中等收率在温和条件下得到相应的 6-羟基-2,3-二氢-1H-茚-1-酮衍生物。
