Equipe Procédés Alimentaires et Physico-Chimie, UMR A 02.102 PAM AgroSup Dijon/Université de Bourgogne, Institut Universitaire de la Vigne et du Vin, Jules Guyot, Rue Claude Ladrey, BP 27877, 21078 Dijon Cedex, France.
Food Chem. 2013 May 1;138(1):270-7. doi: 10.1016/j.foodchem.2012.09.117. Epub 2012 Nov 8.
The aim of this study was to analyze the impact of the water content of wood on the concentrations of volatile compounds which can be extracted after heat treatments. Head Space-Solid Phase Micro Extraction Gas Chromatography coupled to Mass Spectrometry (HS-SPME GC-MS) has been used to compare the concentrations of six aroma compounds (vanillin, furfural, eugenol, guaïacol and cis- and trans-whisky lactones) in hydroalcoholic extracts of heated oak wood samples either previously soaked in hot water or not. Except for eugenol, concentrations of extracted aromas appeared to be lower in soaked woods than in dry woods for temperatures up to 200 °C. If a delaying effect of water could explain such overall lower extracted concentrations from soaked woods, a PCA analysis revealed that for the longer duration (25 min of heat treatment), the adsorbed water could promote a higher impact of furfural, eugenol and both whisky lactones on the composition of hydroalcoholic extracts, suggesting that alternative mechanisms of thermal modifications of the wood macromolecular network could exist at high temperatures in presence of adsorbed water.
本研究旨在分析木材水分含量对热处理后可提取挥发性化合物浓度的影响。采用顶空固相微萃取-气相色谱-质谱联用(HS-SPME-GC-MS)法比较了先前浸泡在热水中的或未浸泡的加热橡木样品的水醇提取物中 6 种香气化合物(香草醛、糠醛、丁香酚、愈创木酚及顺式和反式威士忌内酯)的浓度。除丁香酚外,在 200°C 以下的温度下,浸泡木材的提取香气浓度似乎低于干燥木材。如果水的延迟作用可以解释浸泡木材中提取出的香气浓度总体较低的原因,那么 PCA 分析表明,对于较长的加热时间(25 分钟),吸附水可以促进糠醛、丁香酚和两种威士忌内酯对水醇提取物成分的更大影响,这表明在存在吸附水的情况下,高温下木材大分子量网络的热改性可能存在替代机制。