Kupenko I, Dubrovinsky L, Dubrovinskaia N, McCammon C, Glazyrin K, Bykova E, Boffa Ballaran T, Sinmyo R, Chumakov A I, Potapkin V, Kantor A, Rüffer R, Hanfland M, Crichton W, Merlini M
Bayerisches Geoinstitut Universität Bayreuth, D-95440 Bayreuth, Germany.
Rev Sci Instrum. 2012 Dec;83(12):124501. doi: 10.1063/1.4772458.
The diamond anvil cell (DAC) technique coupled with laser heating is a major method for studying materials statically at multimegabar pressures and at high temperatures. Recent progress in experimental techniques, especially in high-pressure single crystal X-ray diffraction, requires portable laser heating systems which are able to heat and move the DAC during data collection. We have developed a double-sided laser heating system for DACs which can be mounted within a rather small (~0.1 m(2)) area and has a weight of ~12 kg. The system is easily transferable between different in-house or synchrotron facilities and can be assembled and set up within a few hours. The system was successfully tested at the High Pressure Station of White Beam (ID09a) and Nuclear Resonance (ID18) beamlines of the European Synchrotron Radiation Facility. We demonstrate examples of application of the system to a single crystal X-ray diffraction investigation of (Mg(0.87),Fe(3+) (0.09),Fe(2+) (0.04))(Si(0.89),Al(0.11))O(3) perovskite (ID09a) and a Synchrotron Mössbauer Source (SMS) study of (Mg(0.8)Fe(0.2))O ferropericlase (ID18).
金刚石对顶砧(DAC)技术与激光加热相结合,是在多兆巴压力和高温下静态研究材料的主要方法。实验技术的最新进展,尤其是在高压单晶X射线衍射方面,需要便携式激光加热系统,该系统能够在数据收集过程中对DAC进行加热和移动。我们为DAC开发了一种双面激光加热系统,该系统可以安装在相当小的(约0.1平方米)区域内,重量约为12千克。该系统可以在不同的内部或同步加速器设施之间轻松转移,并且可以在几个小时内组装和设置好。该系统已在欧洲同步辐射设施的白光(ID09a)高压站和核共振(ID18)光束线上成功测试。我们展示了该系统在(Mg(0.87),Fe(3+) (0.09),Fe(2+) (0.04))(Si(0.89),Al(0.11))O(3)钙钛矿的单晶X射线衍射研究(ID09a)以及(Mg(0.8)Fe(0.2))O铁方镁石的同步辐射穆斯堡尔源(SMS)研究(ID18)中的应用实例。