Max-Planck-Institut für Kohlenforschung, Mülheim an der Ruhr, Germany.
Angew Chem Int Ed Engl. 2013 Jan 7;52(2):518-33. doi: 10.1002/anie.201205343. Epub 2012 Nov 28.
Recently, the use of enantiomerically pure counteranions for the induction of asymmetry in reactions proceeding through cationic intermediates has emerged as an exciting new concept, which has been termed asymmetric counteranion-directed catalysis (ACDC). Despite its success, the concept has not been fully defined and systematically discussed to date. This Review closes this gap by providing a clear definition of ACDC and by examining both clear cases as well as more ambiguous examples to illustrate the differences and overlaps with other catalysis concepts.
最近，在手性阳离子中间体反应中使用对映体纯的抗衡阴离子诱导不对称反应已成为一个令人兴奋的新概念，该概念被称为不对称抗衡阴离子导向催化（ACDC）。尽管它取得了成功，但该概念尚未得到充分定义和系统讨论。本文通过对 ACDC 的明确定义，并通过检查明确的案例和更模糊的例子来阐明与其他催化概念的差异和重叠，弥补了这一空白。
