双[4-(4-溴苯基亚氨基-κN)戊-2-烯-2-醇根-κO]铜(II)
Bis[4-(4-bromophenylimino-κN)pent-2-en-2-olato-κO]copper(II).
作者信息
Bungu Paul S E, Schutte Marietjie, Steyl G
机构信息
Department of Chemistry, University of the Free State, PO Box 339, Nelson Mandela Drive, Bloemfontein 9301, South Africa.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Nov 1;68(Pt 11):m1373. doi: 10.1107/S1600536812042420. Epub 2012 Oct 20.
In the title compound, [Cu(C(11)H(11)BrNO)(2)], the Cu(II) atom is in a distorted square-planar geometry, with the two bidentate ketimine ligands positioned in a trans geometry. Two inter-molecular C-H⋯O hydrogen bond inter-actions are present which link the mol-ecules in a zigzag manner along the a axis. The mol-ecules pack in layers along the diagonal of the bc plane.
在标题化合物[Cu(C₁₁H₁₁BrNO)₂]中，Cu(II)原子处于扭曲的平面正方形几何构型，两个双齿酮亚胺配体呈反式构型。存在两个分子间C—H⋯O氢键相互作用，它们沿a轴以锯齿状方式连接分子。分子沿bc平面的对角线堆积成层。
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