6-苄基-2-甲基-1,3-双（五氟苯基）-1,3,6,2-三氮杂铝环戊烷
6-Benzyl-2-methyl-1,3-bis-(penta-fluoro-phen-yl)-1,3,6,2-triaza-alumocane.
作者信息
Kireenko Marina M, Zaitsev Kirill V, Churakov Andrei V, Zaitseva Galina S, Karlov Sergey S
机构信息
Department of Chemistry, M.V. Lomonosov Moscow State University, Leninskie Gory 1/3, Moscow 119991, Russian Federation.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Nov 1;68(Pt 11):m1385-6. doi: 10.1107/S1600536812042560. Epub 2012 Oct 20.
In the title compound, [Al(CH(3))(C(23)H(15)F(10)N(3))], the Al(III) atom is coordinated in a distorted tetra-hedral geometry by three N atoms from the tridentate amine and by one C atom of the methyl substituent. Further, there is a short intra-molecular Al⋯F contact [2.5717 (11) Å], leading to an overall distorted trigonal-bipyramidal coordination environment around Al(III).
在标题化合物[Al(CH₃)(C₂₃H₁₅F₁₀N₃)]中，Al(III)原子由三齿胺的三个N原子和甲基取代基的一个C原子以扭曲的四面体几何构型配位。此外，存在一个短的分子内Al⋯F接触[2.5717 (11) Å]，导致Al(III)周围的整体配位环境呈扭曲的三角双锥构型。
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