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μ-氧代-双-{双-[(五氟苯基)甲醇根合](η-五甲基环戊二烯基)钛(IV)}

μ-Oxido-bis-{bis-[(penta-fluoro-phen-yl)methano-lato](η-penta-methyl-cyclo-penta-dien-yl)titanium(IV)}.

作者信息

Lee Junseong, Kim Youngjo

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1104. doi: 10.1107/S1600536811027814. Epub 2011 Jul 16.

DOI:10.1107/S1600536811027814
PMID:22090876
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3212174/
Abstract

The dinuclear title complex, [Ti(2)(C(10)H(15))(2)(C(7)H(2)F(5)O)(4)O], features two Ti(IV) atoms bridged by an O atom. Each Ti atom is bonded to a η(5)-penta-methyl-cyclo-penta-dienyl ring, two (penta-fluoro-phen-yl)methano-late anions and to the bridging O atom. The environment around each Ti atom can be considered as a distorted tetra-hedron.

摘要

双核标题配合物[Ti₂(C₁₀H₁₅)₂(C₇H₂F₅O)₄O]具有由一个O原子桥连的两个Ti(IV)原子。每个Ti原子与一个η⁵-五甲基环戊二烯基环、两个(五氟苯基)甲醇酸根阴离子以及桥连的O原子相连。每个Ti原子周围的环境可视为一个畸变的四面体。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a389/3212174/bbfea25580e8/e-67-m1104-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a389/3212174/3ba9013d019e/e-67-m1104-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a389/3212174/bbfea25580e8/e-67-m1104-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a389/3212174/3ba9013d019e/e-67-m1104-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a389/3212174/bbfea25580e8/e-67-m1104-fig2.jpg

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