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二叔丁基 N-{[1-(吡啶-4-基)-1H-1,2,3-三唑-4-基]甲基}亚氨基二乙酸酯

Di-tert-butyl N-{[1-(pyridin-4-yl)-1H-1,2,3-triazol-4-yl]methyl}iminodiacetate.

作者信息

François Alison, Marty Louise, Picard Claude, Mallet-Ladeira Sonia, Benoist Eric

机构信息

LSPCMIB, UMR-CNRS 5068, Université de Toulouse, 118 route de Narbonne, F-31062 Toulouse cedex 9.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Nov 1;68(Pt 11):o3162. doi: 10.1107/S1600536812042596. Epub 2012 Oct 20.

DOI:10.1107/S1600536812042596
PMID:23284477
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3515257/
Abstract

In the title compound, C(20)H(29)N(5)O(4), the pyridine ring makes a dihedral angle of 10.41 (16)° with the triazole ring, which exhibits an azo-like character. In the crystal, mol-ecules are linked by C-H⋯O and C-H⋯N hydrogen bonds, and C-H⋯π inter-actions involving a methyl group and the pyridine ring of a neighbouring mol-ecule, leading to the formation of a three-dimensional network.

摘要

在标题化合物C₂₀H₂₉N₅O₄中，吡啶环与三唑环形成10.41 (16)°的二面角，该三唑环呈现出类似偶氮的特征。在晶体中，分子通过C—H⋯O和C—H⋯N氢键以及涉及甲基和相邻分子吡啶环的C—H⋯π相互作用相连，从而形成三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ec4e/3515257/7b36fcd8488b/e-68-o3162-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ec4e/3515257/0c8d87854a12/e-68-o3162-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ec4e/3515257/7b36fcd8488b/e-68-o3162-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ec4e/3515257/0c8d87854a12/e-68-o3162-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ec4e/3515257/7b36fcd8488b/e-68-o3162-fig2.jpg

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本文引用的文献

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Pyridine-based lanthanide complexes combining MRI and NIR luminescence activities.基于吡啶的镧系元素配合物兼具 MRI 和 NIR 发光活性。
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