Instituto de Tecnología Química (UPV-CSIC), Universidad Politécnica de Valencia, Avenida de los Naranjos s/n, E-46022, Valencia, Spain.
Chem Soc Rev. 2013 May 7;42(9):4083-97. doi: 10.1039/c2cs35385g. Epub 2013 Jan 4.
Organic-inorganic hybrid materials with different levels of structuration and porous hierarchy and one or several types of active sites in the framework can catalyze multistep chemical processes in a one-pot reactor system following a cascade of reaction events. It will show how the different active sites can act in a synergistic or in a consecutive way following a similar functionality model to biological multisite catalysts. Research on this subject for heterogeneous catalysts is still in the beginning stage and very interesting results can be expected if we are able to successfully combine the properties of organic and inorganic catalysts.
具有不同结构层次和多孔层次的有机-无机杂化材料，以及骨架中的一个或多种类型的活性位，可以在一锅式反应体系中催化多步化学反应，遵循级联反应事件。它将展示不同的活性位如何在协同或连续的方式下作用，遵循类似于生物多部位催化剂的相似功能模型。对于多相催化剂的这一主题的研究仍处于起始阶段，如果我们能够成功地结合有机和无机催化剂的性质，就可以预期得到非常有趣的结果。
