Université Libre de Bruxelles (ULB), Faculté des Sciences, Laboratoire Chimie des Polymères, CP 206/1, Boulevard du Triomphe, 1050 Bruxelles, Belgium.
Org Lett. 2013 Jan 18;15(2):302-5. doi: 10.1021/ol303214j. Epub 2013 Jan 9.
Synthesis, isolation, and characterization of isomerically pure syn- and anti-anthradiindole (ADI) derivatives are described. The anti- and syn-ADI structures are demonstrated by (13)C NMR spectroscopy and by single-crystal X-ray diffraction. The spectroscopic and electrochemical properties as well as the stability of these newly synthesized π-conjugated systems are evaluated and supported by quantum-chemical calculations.
描述了同和反-蒽并吲哚（ADI）衍生物的立体纯异构体的合成、分离和表征。通过（13）C NMR 光谱和单晶 X 射线衍射证明了反式和顺式 ADI 结构。通过量子化学计算评估和支持了这些新合成的π共轭体系的光谱和电化学性质以及稳定性。
