FeCl3 催化的 Prins 型环化反应合成高取代茚：在（±）-jungianol 和 epi-jungianol 全合成中的应用。
FeCl3 catalyzed Prins-type cyclization for the synthesis of highly substituted indenes: application to the total synthesis of (±)-jungianol and epi-jungianol.
机构信息
Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur-208016, India.
出版信息
Org Lett. 2013 Feb 1;15(3):429-31. doi: 10.1021/ol3032347. Epub 2013 Jan 14.
PMID:23317410
Abstract
A novel approach was developed for the synthesis of highly substituted indene derivatives, using an FeCl(3) catalyzed Prins-type cyclization reaction which was further applied in the total synthesis of jungianol and epi-jungianol.
摘要
开发了一种新方法，用于高度取代的茚满衍生物的合成，使用 FeCl(3) 催化的 Prins 型环化反应，该反应进一步应用于 jungianol 和 epi-jungianol 的全合成中。
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