Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, People's Republic of China.
Chem Commun (Camb). 2013 Apr 21;49(31):3171-87. doi: 10.1039/c2cc35637f.
Cyclopentadienyl and substituted cyclopentadienyl ligands are observed in a wide range of organometallic complexes. In addition to serving as ancillary ligands, these ligands have come into their own as intermediates in organometallic reactions, and shown many unique reaction modes involving ring C-H, C-C and C=C bond cleavages. This feature article summarizes the progressive development of cyclopentadienyl-based reactions of metallocene complexes of transition metals and rare-earth metals, with the aim of further developing the fundamental modes of reactivity of such systems together with their synthetic applications.
茂基和取代茂基配体广泛存在于各种金属有机配合物中。除了作为辅助配体外，这些配体本身也已成为金属有机反应中的中间体，并表现出许多涉及环 C-H、C-C 和 C=C 键断裂的独特反应模式。本文综述了过渡金属和稀土金属茂基金属配合物的茂基反应的逐步发展，旨在进一步发展这些体系的基本反应模式及其合成应用。
