Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52056 Aachen (Germany) http://www.ac.rwth-aachen.de/extern/ak-okuda.
Angew Chem Int Ed Engl. 2015 Feb 2;54(6):1724-36. doi: 10.1002/anie.201406677. Epub 2014 Nov 20.
Molecular hydrides of the rare-earth metals play an important role as homogeneous catalysts and as counterparts of solid-state interstitial hydrides. Structurally well-characterized non-metallocene-type hydride complexes allow the study of elementary reactions that occur at rare-earth-metal centers and of catalytic reactions involving bonds between rare-earth metals and hydrides. In addition to neutral hydrides, cationic derivatives have now become available.
稀土金属的分子氢化物作为均相催化剂以及固态间隙型氢化物的对应物起着重要的作用。结构得到很好表征的非茂型氢化物配合物允许研究在稀土金属中心发生的基本反应以及涉及稀土金属和氢化物之间键的催化反应。除了中性氢化物外，现在还可以获得阳离子衍生物。
