2-吡咯烷酮肟在多核过渡金属簇化学中的应用：Fe10 和 Fe12。
2-Pyrrolyloximes in high-nuclearity transition-metal cluster chemistry: Fe10 and Fe12.
机构信息
Department of Chemistry, University of Patras, 265 04 Patras, Greece.
出版信息
Inorg Chem. 2013 Feb 4;52(3):1176-8. doi: 10.1021/ic3023908. Epub 2013 Jan 16.
PMID:23323646
Abstract
The employment of 2-pyrrolyloximes in high-nuclearity transition-metal cluster chemistry has provided access to unprecedented decanuclear and dodecanuclear Fe(III) cagelike clusters bearing the anion of pyrrole-2-carboxaldehyde oxime (praoH(2)), the simplest member of this new family of ligands; the identity of the products depends on the nature of the counteranion present in the starting materials.
摘要
2-吡咯烷酮肟在多核过渡金属簇化学中的应用为获得前所未有的具有吡咯-2-甲醛肟（praoH（2））阴离子的十核和十二核 Fe（III）笼状簇提供了途径，praoH（2）是该新型配体家族的最简单成员；产物的种类取决于起始原料中存在的抗衡阴离子的性质。
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引用本文的文献
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