Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716, United States.
J Am Chem Soc. 2013 Feb 6;135(5):1696-9. doi: 10.1021/ja3112934. Epub 2013 Jan 23.
For a very long time, Ba(16)Ga(32)Sn(104) has been the sole representative of tin clathrates with the type II structure. Herein, we present several new members of this structural family: Cs(8)Ba(16)Ga(39.7(3))Sn(96.3(3)), Rb(9.9(5))Ba(13.3(2))Ga(36.4(3))Sn(99.6(3)), and K(2.0(4))Ba(14.0(4))Ga(30.4(2))Sn(105.6(4)). The successful synthesis of these novel compounds was facilitated through the use of alkali and alkaline-earth metals, which selectively fill the available cages.
在很长一段时间里，Ba(16)Ga(32)Sn(104)一直是具有 II 型结构的锡笼合物的唯一代表。在此，我们介绍该结构家族的几个新成员：Cs(8)Ba(16)Ga(39.7(3))Sn(96.3(3))、Rb(9.9(5))Ba(13.3(2))Ga(36.4(3))Sn(99.6(3))和 K(2.0(4))Ba(14.0(4))Ga(30.4(2))Sn(105.6(4))。这些新型化合物的成功合成得益于碱金属和碱土金属的使用，它们选择性地填充了可用的笼。
