一氧化氮与金属-金属五重键的不同反应性。
Divergent reactivity of nitric oxide with metal-metal quintuple bonds.
机构信息
Department of Chemistry, Frontier Research Center on Fundamental and Applied Sciences of Matters, National Tsing Hua University, Hsinchu, 30013, Taiwan.
出版信息
Chem Commun (Camb). 2013 May 14;49(39):4391-3. doi: 10.1039/c3cc37118b. Epub 2013 Jan 22.
PMID:23337908
Abstract
Reactions of NO with the quintuple bonded chromium and molybdenum amidinate dimers, respectively, gave dichromium nitrosyl nitrito amidinato complexes, and the quadruple bonded dimolybdenum nitrito amidinato species with a paddlewheel configuration.
摘要
分别与五键合铬和钼亚氨基二聚体反应，得到二铬亚硝基亚硝化物酰胺配合物，以及具有桨轮构型的四键合二钼亚硝基亚硝化物酰胺物种。
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