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纳米孪晶金属中孪晶界消除堆垛层错四面体。

Removal of stacking-fault tetrahedra by twin boundaries in nanotwinned metals.

机构信息

Department of Mechanical Engineering, Materials Science and Engineering Program, Texas A&M University, College Station, Texas 77843-3123, USA.

出版信息

Nat Commun. 2013;4:1377. doi: 10.1038/ncomms2382.

Abstract

Stacking-fault tetrahedra are detrimental defects in neutron- or proton-irradiated structural metals with face-centered cubic structures. Their removal is very challenging and typically requires annealing at very high temperatures, incorporation of interstitials or interaction with mobile dislocations. Here we present an alternative solution to remove stacking-fault tetrahedra discovered during room temperature, in situ Kr ion irradiation of epitaxial nanotwinned Ag with an average twin spacing of ~8 nm. A large number of stacking-fault tetrahedra were removed during their interactions with abundant coherent twin boundaries. Consequently the density of stacking-fault tetrahedra in irradiated nanotwinned Ag was much lower than that in its bulk counterpart. Two fundamental interaction mechanisms were identified, and compared with predictions by molecular dynamics simulations. In situ studies also revealed a new phenomenon: radiation-induced frequent migration of coherent and incoherent twin boundaries. Potential migration mechanisms are discussed.

摘要

堆垛层错四面体是面心立方结构的中子或质子辐照结构金属中的有害缺陷。去除它们非常具有挑战性,通常需要在非常高的温度下退火,掺入间隙原子或与可动位错相互作用。在这里,我们提出了一种在室温下原位 Kr 离子辐照具有平均孪晶间距约为 8nm 的外延纳米孪晶 Ag 时发现的去除堆垛层错四面体的替代方法。在与大量相干孪晶界的相互作用过程中,大量的堆垛层错四面体被去除。因此,辐照纳米孪晶 Ag 中的堆垛层错四面体密度远低于其体相的密度。确定了两种基本的相互作用机制,并与分子动力学模拟的预测进行了比较。原位研究还揭示了一种新现象:辐射诱导相干和非相干孪晶界的频繁迁移。讨论了潜在的迁移机制。

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