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用于水体中 Hg2+检测的比色法:从分子到低成本的固态器件。

Colorimetric Hg2+ sensing in water: from molecules toward low-cost solid devices.

机构信息

Institut de Chimie Moléculaire de l'Université de Bourgogne (ICMUB), UMR CNRS 6302, 9 avenue A. Savary, 21078 Dijon Cedex, France.

出版信息

Org Lett. 2013 Feb 1;15(3):662-5. doi: 10.1021/ol303499v. Epub 2013 Jan 23.

Abstract

A new colorimetric molecular sensor allowing for cheap, fast, sensitive, and highly selective naked-eye detection of Hg(2+) in water is described. This molecule combines a 1,8-diaminoanthraquinone signaling subunit and phosphonic acid esters that confer the water solubility to the dye (R = H). A ready-to-use colorimetric solid sensor was obtained by incorporating an amphiphilic analog (R = OC(12)H(25)) exhibiting similar binding properties and optical responses in an agarose film.

摘要

描述了一种新的比色分子传感器,可用于在水中廉价、快速、灵敏且高度选择性地进行肉眼检测 Hg(2+)。该分子结合了 1,8-二氨基蒽醌信号亚基和膦酸酯,使染料具有水溶性(R = H)。通过将具有相似结合特性和光学响应的两亲性类似物(R = OC(12)H(25))掺入琼脂糖膜中,获得了一种即用型比色固态传感器。

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