Institut für Organische Chemie and Center for Nanosystems Chemistry, Universität Würzburg, Würzburg, Germany.
J Am Chem Soc. 2013 Feb 13;135(6):2148-51. doi: 10.1021/ja312628g. Epub 2013 Jan 30.
A new oligophenyleneethynylene (OPE)-based Pd(II) pyridyl complex has been synthesized, and its self-assembly has been investigated in solution, in the bulk state, and on surfaces. Detailed analysis of concentration- and temperature-dependent UV-vis studies in methylcyclohexane supported by DFT calculations demonstrate for the first time that cooperative supramolecular polymerization processes can be driven by metallophilic interactions.
一种新型的基于寡聚苯乙炔（OPE）的 Pd(II) 吡啶配合物已被合成，并对其在溶液、本体和表面中的自组装进行了研究。详细的浓度和温度依赖的紫外-可见研究，并结合密度泛函理论计算，首次证明了金属亲合相互作用可以驱动协同超分子聚合过程。
