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使用涉及 2-氨基-6-硝基苯并噻唑和缩二脲与甲醛的离子键合三元共聚物通过批量平衡技术去除阳离子。

Removal of cations using ion-binding terpolymer involving 2-amino-6-nitro-benzothiazole and thiosemicarbazide with formaldehyde by batch equilibrium technique.

机构信息

Department of Chemistry, Oxford Engineering College, Tiruchirappalli 620 009, Tamil Nadu, India.

出版信息

J Hazard Mater. 2013 Mar 15;248-249:59-68. doi: 10.1016/j.jhazmat.2012.12.047. Epub 2013 Jan 4.

Abstract

2-Amino-6-nitro-benzothiazole and thiosemicarbazide with formaldehyde (BTF) terpolymer was synthesized by the condensation polymerization technique. The elemental analysis and physico-chemical parameters of the terpolymer were measured. This chelation terpolymer was characterized by infrared, electronic and nuclear magnetic resonance ((1)H &(13)C NMR) spectral studies. The molecular weight of the terpolymer was determined by gel permeation chromatography (GPC). Surface analysis of the terpolymer was analyzed by scanning electron microscopy (SEM) and X-ray diffraction (XRD) method. The thermal stability of the terpolymer was analyzed by thermogravimetric analysis (TGA). The cation-exchange property of the terpolymer was determined by batch equilibrium method with the effect of pH, contact time and electrolytes. The reusability of the resin was also studied to estimate the effectiveness of the terpolymer resin.

摘要

2-氨基-6-硝基苯并噻唑和甲醛缩合聚合技术合成了与硫代卡巴肼(BTF)三元共聚物。共聚物的元素分析和物理化学参数进行了测量。该螯合三元共聚物的红外,电子和核磁共振( 1 H和 13 C NMR)谱研究进行了特征化。共聚物的分子量通过凝胶渗透色谱(GPC)确定。扫描电子显微镜(SEM)和X 射线衍射(XRD)法对共聚物的表面分析。通过热重分析(TGA)对共聚物的热稳定性进行了分析。采用间歇平衡法,通过 pH 值、接触时间和电解质的影响,测定了共聚物的离子交换性能。还研究了树脂的重复使用性,以评估共聚物树脂的有效性。

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