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一种前所未有的动态多孔金属-有机骨架,由五重互锁的闭合纳米管组装而成,具有选择性气体吸附行为。

An unprecedented dynamic porous metal-organic framework assembled from fivefold interlocked closed nanotubes with selective gas adsorption behaviors.

机构信息

MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.

出版信息

Chem Commun (Camb). 2013 Mar 4;49(18):1820-2. doi: 10.1039/c3cc38519a. Epub 2013 Jan 28.

Abstract

An unprecedented 3D dynamic porous metal-organic framework assembled from fivefold interlocked closed nanotubes has been constructed, which exhibits highly selective adsorption of CO(2) over N(2) and H(2), as well as stepwise and hysteretic behaviors.

摘要

一种前所未有的由五重互锁封闭纳米管组装而成的 3D 动态多孔金属有机骨架已经构建,它对 CO(2)具有高度选择性的吸附作用,对 N(2)和 H(2)的吸附则呈现逐步和滞后的行为。

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