一种基于多个螺旋的含有纳米管的 3D 多孔金属有机骨架。

A 3D porous metal-organic framework containing nanotubes based on multiple helices.

机构信息

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Materials Science Northwest University, Xi'an 710069, China.

出版信息

Dalton Trans. 2013 May 14;42(18):6306-9. doi: 10.1039/c3dt50506e.

DOI:10.1039/c3dt50506e

PMID:23532443

Abstract

Combining Co2 clusters with mixed H2bpdc and H2bpz ligands creates an unprecedented 3-fold interpenetrated 5-connected porous framework, which possesses the fascinating double-walled nanotubes structure assembled from nonuple and triple helices, and exhibits gas sorption properties.

摘要

将 CO2 簇与混合的 H2bpdc 和 H2bpz 配体结合，创造了一个前所未有的 3 重互穿的 5 连接多孔骨架，具有由非九元和三螺旋组成的迷人的双层纳米管结构，并表现出气体吸附性能。