利用离子淌度质谱（IMS-MS）对多金属氧酸盐 Keplerate 簇及其超分子组装进行映射。
Use of ion-mobility mass spectrometry (IMS-MS) to map polyoxometalate Keplerate clusters and their supramolecular assemblies.
机构信息
WestCHEM, School of Chemistry, University of Glasgow, Glasgow, G12 8QQ, Scotland, UK.
出版信息
Chem Commun (Camb). 2013 Mar 7;49(19):1909-11. doi: 10.1039/c3cc38615e. Epub 2013 Jan 30.
We present the high-resolution (HRES-MS) and ion-mobility (IMS-MS) mass spectrometry studies of icosahedral nanoscale polyoxometalate-based {L(30)}{(Mo)Mo(5)} Keplerate clusters, and demonstrate the use of IMS-MS to resolve and map intact nanoclusters, and its potential for the discovery of new structures, in this case the first gas phase observation of 'proto-clustering' of higher order Keplerate supramolecular aggregates.
我们呈现了基于二十面体纳米多金属氧酸盐的 {L(30)}{(Mo)Mo(5)} Keplerate 团簇的高分辨率（HRES-MS）和离子迁移（IMS-MS）质谱研究，并展示了 IMS-MS 在解析和映射完整纳米团簇方面的应用，以及其在发现新结构方面的潜力，在这种情况下，首次在气相中观察到更高阶 Keplerate 超分子聚集体的“原聚类”。
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