在水中利用疏水作用和氢键形成进行超分子聚合。
Supramolecular polymerization in water harnessing both hydrophobic effects and hydrogen bond formation.
机构信息
Institute for Complex Molecular Systems, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands.
出版信息
Chem Commun (Camb). 2013 Mar 7;49(19):1963-5. doi: 10.1039/c3cc38949a. Epub 2013 Jan 31.
PMID:23364450
Abstract
The formation of supramolecular polymers in water through rational design of a benzene-1,3,5-tricarboxamide (BTA) motif is presented. Intermolecular hydrogen bonding and hydrophobic effects cooperate in the self-assembly into long fibrillar aggregates. Minimal changes in molecular structure significantly affect the internal packing of the aggregates.
摘要
通过合理设计苯-1,3,5-三羧酰胺（BTA）基序，在水中形成超分子聚合物。分子间氢键和疏水作用共同作用于自组装成长纤维状聚集体。分子结构的微小变化显著影响聚集体的内部堆积。
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