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在最短的硼(III)-氧键上。

On the shortest B(III)-O bonds.

作者信息

Sidey Vasyl

机构信息

Department of Chemistry and Research Institute for Physics and Chemistry of Solids, Uzhgorod National University, Pidgirna Street 46, Uzhgorod 88000, Ukraine.

出版信息

Acta Crystallogr B. 2013 Feb;69(Pt 1):86-9. doi: 10.1107/S0108768112051506. Epub 2013 Jan 19.

Abstract

For the crystal structures of oxoborates, the value of ~1.2 Å can be regarded as the lower physical limit for B(III)-O bond lengths. The oxoborate crystal structures with B(III)-O bond lengths shorter than ~1.2 Å have been found to be either doubtful or clearly erroneous.

摘要

对于硼酸盐的晶体结构,约1.2 Å的值可被视为B(III)-O键长的下限物理值。已发现B(III)-O键长小于约1.2 Å的硼酸盐晶体结构要么存疑,要么明显错误。

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