用锌(II)和原位生成的碳二膦烷将二氧化碳催化还原为一氧化碳。
Catalytic reduction of CO(2) to CO by using zinc(II) and in situ generated carbodiphosphoranes.
机构信息
Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, M5S 3H6, Canada.
出版信息
Angew Chem Int Ed Engl. 2013 Feb 25;52(9):2516-9. doi: 10.1002/anie.201208817. Epub 2013 Jan 31.
PMID:23364808
Abstract
Playing it 'CO'ol: CO(2) is catalytically reduced to CO with concurrent oxidation of phosphine to phosphineoxide by using an in situ generated catalyst derived from a carbodiphosphorane and zinc(II).
摘要
通过使用原位生成的催化剂，将二膦（carbodiphosphorane）和锌（II）反应生成的催化剂，将 CO2 催化还原为 CO，同时将磷化氢氧化为氧化膦。
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