在有氧条件下，三芳基膦在固定于纳米纤维磷硅酸盐上的纤维素负载的金（III）配合物存在下的光氧化反应。
Photooxidation of triarylphosphines under aerobic conditions in the presence of a gold(iii) complex on cellulose extracted from immobilized on nanofibrous phosphosilicate.
作者信息
Sadeghzadeh Seyed Mohsen, Zhiani Rahele
机构信息
New Materials Technology and Processing Research Center, Department of Chemistry, Neyshabur Branch, Islamic Azad University Neyshabur Iran
Young Researchers and Elite Club, Neyshabur Branch, Islamic Azad University Neyshabur Iran.
出版信息
RSC Adv. 2019 Jan 11;9(3):1509-1516. doi: 10.1039/c8ra09721f. eCollection 2019 Jan 9.
Triarylphosphines were converted to the corresponding oxides photooxidation as a novel method. In this study, cellulose was extracted from the plant and then oxidized by sodium metaperiodate. A gold complex was supported on this natural cellulose. Then, a gold complex on natural cellulose supported on FPS (FPS/Au(iii)) was synthesized for the reduction of phosphine oxides to corresponding phosphines with remarkable chemoselectivity. The morphology of FPS led to higher catalytic activity. FPS/Au(iii) NPs were thoroughly characterized using TEM, FESEM, FTIR, TGA, and BET.
三芳基膦通过光氧化转化为相应的氧化物，这是一种新方法。在本研究中，从植物中提取纤维素，然后用过碘酸钠进行氧化。在这种天然纤维素上负载金配合物。然后，合成了负载在FPS上的天然纤维素上的金配合物（FPS/Au(iii)），用于将氧化膦选择性地还原为相应的膦。FPS的形态导致了更高的催化活性。使用TEM、FESEM、FTIR、TGA和BET对FPS/Au(iii)纳米颗粒进行了全面表征。
Zotero 插件