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J Magn Reson. 2013 Mar;228:104-15. doi: 10.1016/j.jmr.2012.12.009. Epub 2013 Jan 9.
In the past decade, low-field NMR relaxation and diffusion measurements in grossly inhomogeneous fields have been used to characterize properties of porous media, e.g., porosity and permeability. Pulse sequences such as CPMG, inversion and saturation recovery as well as diffusion editing have been used to estimate distribution functions of relaxation times and diffusion. Linear functionals of these distribution functions have been used to predict petro-physical and fluid properties like permeability, viscosity, fluid typing, etc. This paper describes an analysis method using integral transforms to directly compute linear functionals of the distributions of relaxation times and diffusion without first computing the distributions from the measured magnetization data. Different linear functionals of the distribution function can be obtained by choosing appropriate kernels in the integral transforms. There are two significant advantages of this approach over the traditional algorithm involving inversion of the distribution function from the measured data. First, it is a direct linear transform of the data. Thus, in contrast to the traditional analysis which involves inversion of an ill-conditioned, non-linear problem, the estimates from this new method are more accurate. Second, the uncertainty in the linear functional can be obtained in a straight-forward manner as a function of the signal-to-noise ratio (SNR) in the measured data. We demonstrate the performance of this method on simulated data.
在过去的十年中,在宏观不均匀场中进行的低场 NMR 弛豫和扩散测量已被用于表征多孔介质的性质,例如孔隙率和渗透率。已经使用诸如 CPMG、反转和饱和恢复以及扩散编辑之类的脉冲序列来估计弛豫时间和扩散的分布函数。这些分布函数的线性泛函已被用于预测岩石物理和流体性质,例如渗透率、粘度、流体类型等。本文描述了一种使用积分变换的分析方法,该方法无需先从测量的磁化数据计算分布,即可直接计算弛豫时间和扩散分布的线性泛函。通过在积分变换中选择适当的核函数,可以获得分布函数的不同线性泛函。与涉及从测量数据反演分布函数的传统算法相比,该方法有两个显著优势。首先,它是数据的直接线性变换。因此,与传统分析涉及反演病态非线性问题相比,该新方法的估计更准确。其次,可以直接将线性泛函的不确定性作为测量数据中信噪比(SNR)的函数获得。我们在模拟数据上演示了该方法的性能。