Department of Chemical and Biological Engineering, University of Colorado at Boulder, Boulder, CO 80309-0596, USA.
Adv Mater. 2013 Apr 11;25(14):2024-8. doi: 10.1002/adma.201203815. Epub 2013 Feb 11.
The first bulk photopolymerization of multifunctional alkyne and azide monomers using the CuAAC reaction is successfully carried out from low molecular weight, nonviscous monomer resins. Compared to other traditional step-growth bulk photopolymerization, this approach readily provides crosslinked, high glass transition temperature polymers that incorporate triazole linkages throughout the polymer structure with great temporal control.
首次成功地使用铜催化的点击化学反应进行了低分子量、非粘性单体树脂的多功能炔烃和叠氮单体的批量光聚合。与其他传统的逐步聚合体批量光聚合相比，这种方法可以轻松地提供交联的、玻璃化转变温度高的聚合物，这些聚合物在聚合物结构中具有三唑键，并且具有很好的时间控制。
