Institute of Environmental Health, National Taiwan University, Taiwan.
Sci Total Environ. 2013 Apr 1;449:20-8. doi: 10.1016/j.scitotenv.2013.01.038. Epub 2013 Feb 10.
Occurrence and methods for the removal of nonylphenolic compounds in drinking water have been gaining increased attention due to their widespread presence in natural water and the potential health risks from the consumptions of drinking water. The purpose of this study was to assess the occurrence of nonylphenol (NP), octylphenol (OP), and bisphenol-A (BPA) in water sources and treated water in Taiwan, to evaluate the treatment efficiencies of these compounds in both the conventional (coagulation, sedimentation, filtration and chlorination) and advanced treatment processes. The treatment efficiencies of these chemicals were assessed based on their concentrations in water sources, and the results were verified with laboratory simulated treatment processes. A survey of NP, OP, and BPA in 11 Taiwanese water sources showed that all of them could be identified in most of the sampled sources, and that higher concentrations of NP were found when the raw water was contaminated by domestic wastewater. However, higher treatment efficiency could be observed when the NP concentration in water source is high. Laboratory simulation studies of conventional treatment processes showed that chlorination played an important role in the degradation of NP in raw water. Treatment efficiencies of 60%-90% were achieved for NP removal when sufficient chlorine dosages were applied to satisfy chlorine demands. However, results also showed that conventional coagulation and rapid filtration processes were less effective in the reduction of phenolic compounds in water.
由于壬基酚化合物在天然水中的广泛存在及其对饮用水消费可能带来的健康风险,饮用水中去除壬基酚化合物的方法越来越受到关注。本研究旨在评估台湾水源水和处理水中壬基酚(NP)、辛基酚(OP)和双酚 A(BPA)的含量,评估这些化合物在常规(混凝、沉淀、过滤和氯化)和先进处理工艺中的去除效率。根据水源水中这些化学物质的浓度评估了它们的处理效率,并通过实验室模拟处理过程对结果进行了验证。对台湾 11 个水源水中的 NP、OP 和 BPA 的调查表明,它们都可以在大多数采样源中被识别出来,而且当原水受到生活污水污染时,NP 的浓度更高。然而,当水源中 NP 浓度较高时,可以观察到更高的处理效率。常规处理工艺的实验室模拟研究表明,氯化在原水中 NP 的降解中起着重要作用。当应用足够的氯剂量以满足氯需求时,NP 的去除率可达到 60%-90%。然而,结果还表明,常规混凝和快速过滤工艺对水中酚类化合物的去除效果较差。