Copernicus Institute, Utrecht University, Budapestlaan 6, Utrecht 3584 CD, The Netherlands.
Nanoscale Res Lett. 2013 Feb 15;8(1):81. doi: 10.1186/1556-276X-8-81.
The possibility to tune chemical and physical properties in nanosized materials has a strong impact on a variety of technologies, including photovoltaics. One of the prominent research areas of nanomaterials for photovoltaics involves spectral conversion. Modification of the spectrum requires down- and/or upconversion or downshifting of the spectrum, meaning that the energy of photons is modified to either lower (down) or higher (up) energy. Nanostructures such as quantum dots, luminescent dye molecules, and lanthanide-doped glasses are capable of absorbing photons at a certain wavelength and emitting photons at a different (shorter or longer) wavelength. We will discuss upconversion by lanthanide compounds in various host materials and will further demonstrate upconversion to work for thin-film silicon solar cells.
纳米材料中化学和物理性质的可调谐性对包括光伏在内的各种技术有重大影响。用于光伏的纳米材料的突出研究领域之一涉及光谱转换。光谱的修饰需要下转换和/或上转换或下转换,这意味着光子的能量被修改为更低(下)或更高(上)的能量。量子点、发光染料分子和镧系掺杂玻璃等纳米结构能够在特定波长处吸收光子,并在不同(更短或更长)波长处发射光子。我们将讨论各种基质材料中镧系化合物的上转换,并进一步证明上转换可用于薄膜硅太阳能电池。