在氧化条件下使用 N-杂环卡宾进行催化。
Catalysis with N-heterocyclic carbenes under oxidative conditions.
机构信息
Institute of Organic Chemistry, Westfälische Wilhelms-University, Corrensstrasse 40, 48149 Münster, Germany.
出版信息
Chemistry. 2013 Apr 8;19(15):4664-78. doi: 10.1002/chem.201203707. Epub 2013 Feb 21.
PMID:23436489
Abstract
This Concept article discusses the potential of oxidative carbene catalysis in synthesis and comprehensively covers pioneering studies as well as recent developments. Oxidative carbene catalysis can be conducted by using inorganic and organic oxidants. Applications in cascade processes, in enantioselective catalysis, and also in natural product synthesis are discussed.
摘要
这篇述评文章讨论了氧化卡宾催化在合成中的潜力，并全面涵盖了开创性研究和最新进展。氧化卡宾催化可以使用无机和有机氧化剂来进行。还讨论了其在级联反应、对映选择性催化以及天然产物合成中的应用。
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