Gül H, Akbulut H, Aslan S, Alp A
Gumusova Vocational School Department of Metallurgy, Düzce University, Gumusova 81850, Duzce.
J Nanosci Nanotechnol. 2012 Dec;12(12):9076-87. doi: 10.1166/jnn.2012.6748.
In the present work, Ni/SiC metal matrix composite (MMC) coatings were prepared from a modified Watt's type electrolyte containing nano-SiC particles by direct current (DC) plating method to increase wear resistance of the electro co-deposited Ni. SiC nano particles with average particle size of 0, 1-1 microm were co-deposited with nickel matrix on the steel substrates. For this purpose, several studies were carried out to optimize deposition parameters for specific applications. The depositions were controlled to obtain the specific thickness (between 175-200 microm) and particle volume fraction in the matrix (between 0.03 and 0.10). The hardness of the resultant coatings was measured and found to be 280-571 HV depending on the particle concentration in the electrolyte and therefore, particle volume in the Ni matrix. The tribological tests were performed by a reciprocating ball-on disk apparatus sliding against M50 steel ball (Ø10 mm). All the friction and wear tests were performed under the unlubricated conditions at room temperature and in the ambient air (relative humidity 55-65%). The wear tests were carried out at different sliding velocities of 50 mm/s, 100 mm/s and 150 mm/s by using a constant dead load of 1.0 N. It was detected that increasing sliding speed resulted to increase wear rate but decreasing friction coefficient due to change in wear mechanism. Increasing sliding speed showed formation of tribo induced oxides up to 20 g/l SiC(p) in the electrolyte and wear mechanism was controlled by temperature induced fatigue wear. Further increase in the SiC(p) in the electrolyte caused an abrasive type of the wear.
在本研究中,采用直流电镀法,从含有纳米碳化硅颗粒的改良瓦特型电解液中制备镍/碳化硅金属基复合材料(MMC)涂层,以提高电共沉积镍的耐磨性。平均粒径为0.1 - 1微米的碳化硅纳米颗粒与镍基体共沉积在钢基体上。为此,开展了多项研究以优化特定应用的沉积参数。沉积过程得到控制,以获得特定的厚度(175 - 200微米之间)和基体中的颗粒体积分数(0.03至0.10之间)。测量了所得涂层的硬度,发现其硬度在280 - 571 HV之间,这取决于电解液中的颗粒浓度,进而取决于镍基体中的颗粒体积。摩擦学测试通过往复式球盘装置进行,该装置与M50钢球(直径10毫米)滑动摩擦。所有摩擦和磨损测试均在室温下的无润滑条件及环境空气中(相对湿度55 - 65%)进行。磨损测试在50毫米/秒、100毫米/秒和150毫米/秒的不同滑动速度下进行,使用1.0 N的恒定静载。结果发现,由于磨损机制的变化,滑动速度增加导致磨损率上升,但摩擦系数下降。滑动速度增加表明,电解液中碳化硅颗粒含量高达20克/升时会形成摩擦诱导氧化物,磨损机制受温度诱导疲劳磨损控制。电解液中碳化硅颗粒含量进一步增加会导致磨料磨损。